|
Section
1: Product and Company Information
|
|
Product Name(s)
|
Vermilion,
Cinnabar
|
|
Product Number(s)
|
450-11S,
450-15S
|
|
Company
|
Natural
Pigments LLC
PO Box 112
Willits, CA 95490
United States of America
|
|
Technical Phone
|
707-459-9998
|
|
Fax
|
408-516-9442
|
|
Section
2: Composition / Information on Ingredients
|
|
Product Name
|
Vermilion,
Cinnabar
|
|
Synonyms
|
English
Vermilion, Chinese Vermilion, French Vermilion, red mercuric sulfide, red
sulfuretted oxide of mercury; liver ore; Zinnober (Deut.); Zinnoberersatz
(Ned.); cinabrio (Esp.); cinabre (Fr.); cinabro (It.); cin·brio (Port.);
shinsha (Jap.); tan-sha (Chin.); sulfure de mercure (Fr.)
|
|
Colour Index
|
Pigment
Red 106 (77766)
|
|
CAS No.
|
1344-48-5
|
|
Component
Name
|
CAS No.
|
% Composition Range
|
OSHA PEL mg/m3
|
ACGIH TLV mg/m3
|
DFG-MAK mg/m3
|
|
|
|
|
TWA
|
STEL
|
TWA
|
STEL
|
TWA
|
STEL
|
|
Mercuric
Sulfide (HgS)
|
1344-48-5
|
>98%
|
N.E.1
|
N.E.
|
N.E.
|
N.E.
|
N.E.
|
N.E.
|
|
Mercury
Compounds
|
|
|
1
|
N.E.
|
0.1
|
N.E.
|
N.E.
|
N.E.
|
|
1) N.E. = None
Established
|
|
|
Section
3: Hazards Identification
|
|
Overview
|
Mercury
is a general protoplasmic poison; after absorption it circulates in the
blood and is stored in the liver, kidneys, spleen, and bone. In industrial
poisoning, the principal effect is upon the central nervous system, the
mouth, and gums. The cardinal symptoms of industrial mercury poisoning are
stomatitis, tremors, and psychic disturbances. In humans, it is readily
absorbed by the respiratory tract, intact skin, and the gastrointestinal
tract. Occasional incidental swallowing of metallic mercury may be without harm.
Spilled and heated elemental mercury is particularly hazardous. A number of
mercury compounds, in addition to the fulminate, can cause skin irritation
and be absorbed through the skin. They are strong allergens and common air
contaminants (Sax, Dangerous Properties of Industrial Materials, 8th edition).
|
|
Potential
Acute Health Effects
|
|
Eyes
|
Hazardous
in case of eye contact (irritant).
|
|
Skin
|
Hazardous
in case of skin contact (irritant, sensitizer and permeator).
|
|
Inhalation
|
Hazardous
in case of inhalation.
|
|
Ingestion
|
Extremely
hazardous in case of ingestion. Severe over-exposure can result in death.
Mercuric sulfide LD50: Not Available. LC50: Not Available.
|
|
Potential
Chronic Health Effects
|
|
Eyes
|
Hazardous
in case of eye contact (irritant).
|
|
Skin
|
Hazardous
in case of skin contact (irritant, sensitizer and permeator).
|
|
Inhalation
|
Hazardous
in case of inhalation.
|
|
Ingestion
|
Extremely
hazardous in case of ingestion. Severe over-exposure can result in death.
CARCINOGENIC
EFFECTS: Classified A5 (Not suspected for human.) by ACGIH.
MUTAGENIC
EFFECTS: Not available.
TERATOGENIC
EFFECTS: Not available.
DEVELOPMENTAL
TOXICITY: Not available.
The
substance is toxic to kidneys, lungs, the nervous system, mucous membranes.
Repeated or prolonged exposure to the substance can produce target organs
damage. Repeated exposure to an highly toxic material may produce general
deterioration of health by an accumulation in one or many human organs.
|
|
Section 4: First Aid Measures
|
|
After Inhalation
|
Remove
to fresh air. If breathing is labored or stopped, give artificial
respiration. Seek immediate medical attention. WARNING: It may be hazardous
to the person providing aid to give mouth-to-mouth resuscitation when the
inhaled material is toxic, infectious or corrosive.
|
|
After Skin Contact
|
After
contact with skin, wash immediately with plenty of water. Gently and
thoroughly wash the contaminated skin with running water and non-abrasive
soap. Be particularly careful to clean folds, crevices, creases and groin. Cover
the irritated skin with an emollient. If irritation persists, seek medical
attention. Wash contaminated clothing before reusing.
|
|
After Eye Contact
|
Check
for and remove any contact lenses. Flush eyes with plenty of water for at
least 15 minutes. Do not use an eye ointment. Seek medical attention.
|
|
After Ingestion
|
Do
not induce vomiting. Examine the lips and mouth to ascertain whether the
tissues are damaged, a possible indication that the toxic material was
ingested; the absence of such signs, however, is not conclusive. Loosen tight
clothing such as a collar, tie, belt or waistband. If the victim is not
breathing, perform mouth-to-mouth resuscitation. Seek immediate medical
attention.
|
|
Section
5: Fire Fighting Measures
|
|
Fire
|
Not
considered to be a fire hazard. Not flammable. May be combustible at high
temperature.
|
|
Explosion
|
Not
considered to be an explosion hazard.
|
|
Extinguishing Media
|
This
material is not combustible and is not anticipated to react with
commercially employed extinguishing media. Use appropriate extinguishing
media for surrounding fire.
|
|
Section
6: Accidental Release Measures
|
|
Spill Procedures
|
Protect
against identified hazards through use of prescribed personal protection
equipment, proper work and hygiene practices. Limit foot and vehicular
traffic to minimize mechanical agitation and dispersion. Employ a vacuum,
equipped with HEPA (High Efficiency Particulate Air) filter, for cleanup of
the spill material. If no vacuum is available, use a broom and shovel to
collect excess powder in the area. Recover uncontaminated material for use.
Vacuum or sweep remaining material keeping dust to a minimum. Residual
material should then be cleared, utilizing the process of wet sweeping, to
avoid dust generation.
|
|
Containment Techniques
|
This
is a solid material and will not travel far from the spill location unless
mechanically agitated.
|
|
Spill Response Equipment
|
The
following equipment is recommended for spill response:
vacuum, equipped with a HEPA filter
broom, wet mop
dustpan, shovel, or scoop
bags, drums or sacks for collection
|
|
Personal Protective Equipment
|
All
personnel should utilize the following protective equipment when performing
spill response activities:
gloves (rubber or leather)
safety glasses or goggles
respiratory equipment as recommended in Section 8
|
|
Section
7: Handling and Storage
|
|
Storage
|
Keep
locked up. Keep away from heat. Keep away from sources of ignition. Empty
containers pose a fire risk, evaporate the residue under a fume hood.
Ground all equipment containing material. Do not ingest. Do not breathe
dust. Wear suitable protective clothing In case of insufficient
ventilation, wear suitable respiratory equipment. If ingested, seek medical
advice immediately and show the container or the label. Avoid contact with skin
and eyes.
|
|
Handling
|
When
handling this product, all personnel are directed to:
Wear all specified elements of PPE, as directed by this document, or
under location specific requirements, whichever is more conservative.
Avoid creating dust, where possible.
|
|
Section
8: Exposure Controls / Personal Protection
|
|
Engineering Controls
|
Use
with adequate ventilation to meet exposure limits listed in Section 2.
|
|
Respiratory Protection
|
Use
NIOSH-approved dust respirator, if overexposure exists.
|
|
Skin Protection
|
Leather
or rubber gloves.
|
|
Eye/Face Protection
|
Safety
glasses, goggles or face shield are recommended.
|
|
Work Hygiene Practices
|
To
control potential exposures, avoid creating dust.
Do not eat, drink, smoke, or perform other hand-to-mouth activities in
product use or handling area.
Wash thoroughly after handling this product.
|
|
Section
9: Physical and Chemical Properties
|
|
Appearance
|
Physical
State: Solid
Color: Red
Form: Powder
|
|
Odor
|
Odorless
|
|
Molecular Weight
|
232.65
g/mole
|
|
Melting Point
|
583 C
(1081.4 F)
|
|
Specific Gravity
|
8.1
(Water = 1)
|
|
Solubility
|
Insoluble
in cold water.
|
|
Section
10: Stability and Reactivity
|
|
Stability
|
Stable
under ordinary conditions of use and storage.
|
|
Hazardous Decomposition Products
|
Not
available.
|
|
Hazardous Polymerization Products
|
Not
available.
|
|
Incompatibilities
|
Not
available.
|
|
Conditions to Avoid
|
Not
available.
|
|
Section
11: Toxicological Information
|
|
Routes of Entry
|
Absorbed
through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
|
|
Toxicity to Animals
|
LD50:
Not available.
LC50:
Not available.
|
|
Chronic Effects on Humans
|
CARCINOGENIC
EFFECTS: Classified A5 (Not suspected for human.) by ACGIH.
The
substance is toxic to kidneys, lungs, the nervous system, mucous membranes.
|
|
Other Toxic Effects on Humans
|
Extremely
hazardous in case of ingestion. Hazardous in case of skin contact
(irritant, sensitizer, permeator), of inhalation.
|
|
Section
12: Ecological information
|
|
Ecotoxicity
|
Not
available.
|
|
Products of Biodegradation
|
Possibly
hazardous short term degradation products are not likely. However, long
term degradation products may arise.
|
|
Toxicity of the Products of Biodegradation
|
The
products of degradation are more toxic.
|
|
Remarks on the Products of Biodegradation
|
Not
available.
|
|
Section
13: Disposal Considerations
|
|
Recommended Disposal Method
|
Collect
in containers, bags or covered dumpster boxes. Whatever cannot be saved for
recovery or recycling should be managed in an appropriate and approved
waste disposal facility. Processing, use or contamination of this product
may change the waste management options. State and local disposal
regulations may differ from federal disposal regulations. Dispose of
container and unused contents in accordance with federal, state and local
requirements.
|
|
Section
14: Transportation Information
|
|
DOT Classification
|
CLASS
6.1: Poisonous material.
Marine
Pollutant
|
|
Identification
|
Mercury
compound, solid, n.o.s. (Mercuric sulfide): UN2025 PG: III
|
|
Special Provisions
|
Marine
Pollutant
|
|
Section
15: Regulatory Information
|
|
SARA 313 Title III
|
Section
313 toxic chemical notification and release reporting: Mercuric sulfide.
|
|
OSHA Status
|
Hazardous
by definition of Hazard Communication Standard (29 CFR 1910.1200).
|
|
TSCA Status
|
8(b)
inventory: Mercuric sulfide.
|
|
California Proposition 65
|
This
product contains the following ingredients for which the State of
California has found to cause cancer, birth defects or other reproductive
harm, which would require a warning under the statute: Mercuric sulfide.
This
product contains the following ingredients for which the State of
California has found to cause birth defects which would require a warning
under the statute: Mercuric sulfide.
|
|
CERCLA Reportable Quantity
|
Hazardous
substances.: Mercuric sulfide.
|
|
International Regulations
|
WHMIS
(Canada) CLASS D-1B: Material causing immediate and serious toxic effects
(TOXIC).
WHMIS
(Canada) CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL
(European Economic Community): R36/38-Irritating to eyes and skin.
R43-May
cause sensitization by skin contact.
|
|
HMIS (USA)
|
Health:
2
Flammability:
1
Reactivity:
0
Protective
Equipment: E
|
|
Section
16: Other Information
|
|
Date
|
1
August 2008
|
|
|
The
above information is believed to be correct but does not purport to be all
inclusive and shall be used only as a guide. The information in this
document is based on the present state of our knowledge and is applicable
to the product with regard to appropriate safety precautions. It does not
represent any guarantee of the properties of the product. Natural Pigments,
LLC shall not be held liable for any damage resulting from handling or from
contact with the above product.
Copyright 2008 Natural Pigments, LLC. License granted to make unlimited
paper copies for internal use only.
|
