Diarylide Yellow Pigment

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SKU
436-11

Diarylide Yellow is a high-performance red-shade yellow azo pigment, that is more opaque, has good tinting strength, and enhanced outdoor durability. Diarylide Yellow (PY83) pigments offer better solvent and migration resistance than monoazo yellow pigments making them a good pigment for inks, plastics, and paint. Our Diarylide yellow is a reddish-yellow pigment recommended for paints as an alternative to replace reddish shade chrome yellows to produce lead-free paints as well as for inks.

Diarylide Yellow is a high-performance red-shade yellow azo pigment, that is more opaque, has good tinting strength, and enhanced outdoor durability. Diarylide Yellow (PY83) pigments offer better solvent and migration resistance than monoazo yellow pigments making them a good pigment for inks, plastics, and paint. Our Diarylide yellow is a reddish-yellow pigment recommended for paints as an alternative to replace reddish shade chrome yellows to produce lead-free paints as well as for inks.

Pigment Information
Color:Yellow
Pigment Classification:Synthetic Organic
Colour Index:Pigment Yellow 83 (21108)
Chemical Name:Diarylide Yellow (3,3' dichlorobenzidine coupled with acetoacet-4-methoxy-5-chloro-o-anisidide)
Chemical Formula:C36H32Cl4N6O8
Chemical Structure:Diarylide Chemical Structure
CAS No.:5567-15-7
Series No.:4
ASTM Lightfastness
Acrylic:I
Oil:I
Watercolor:I
Physical Properties
Specific Surface:20 m2/g
Density:1.5 g/cm3
Bulk Volume:4.3 l/kg
Refractive Index:1.721
Oil Absorption:58 ml oil / 100 grams pigment
Health and SafetyThere are no acute or known chronic health hazards associated with the anticipated use of this product (most chemicals are not fully tested for chronic toxicity). Always protect yourself against potentially unknown chronic hazards of this and other chemical products by keeping them out of your body. Do this by avoiding ingestion, excessive skin contact, and inhalation of spraying mists, sanding dust, and vapors from heating. Conforms to ASTM D-4236.


For a detailed explanation of the terms in the table above, please visit Composition and Permanence.

Origin and History

The first azo pigment, tartrazine yellow, PY100, which is still used in artists’ paints, was patented in 1884. β-naphthol azo pigments were first introduced from 1895 to 1911, and they are still in production. The first Hansa yellow, PY1, was patented in 1909, and the first diarylide was synthesized in 1911. Because their importation from Germany was forbidden during World War I, American manufacturers began to study azo dyes in depth. Azo pigments have become the largest class of synthetic organic pigments because of their ease of preparation and wide range of colors. Diarylide yellow pigments are made in a color range from greenish- to reddish-yellow shades.

Diarylides were not widely used until almost twenty-five years after their synthesis in 1911. At that time, they were sold as pigments for rubber under the trade names Vulcan Fast Yellows and Oranges. Diarylides are an important class of azo pigments and now account for approximately 80 percent of all yellow pigments. They are primarily used in printing inks, where twenty-five thousand metric tons were used in 1989. 

Diarylide Yellow, PY83, also known as Permanent Yellow HR, is more non-bleeding and lightfast than other diarylide yellows. It was introduced in 1958 by Hoechst and is a reddish yellow pigment used in plastics, printing, and artists’ colors.

PyrazoloneColour Index No.NaphtholColour Index No.β-NaphtholColour Index No.Arylide (Hansa)Colour Index No.DiarylideColour Index No.Nickel-Azo YellowColour Index No.BenzimidazoloneColour Index No.
PO1321110PO3812367PO212060PO111725PY1221090PG1012775PBr2512510
PY10019140PR112070PO512075PY111680PY1321110PO3611780
PR212310PO1715510PY311710PY1421095PO6011782
PR512490PR312120PY411665PY1721105PO6211775
PR712420PR412085PY511660PY5521096PR17112512
PR812335PR612090PY911720PY8121127PR17512513
PR912460PR4815865PY6511740PY8321108PR17612515
PR1212385PR4915630PY7311738PY15113980
PR1412380PR5215860PY7411741PY15348545
PR1712390PR5315585PY7511770PY15411781
PR1812350PR5715850PY9711767PY17511784
PR2212315PR6016105PY9811727
PR2312355
PR3112360
PR11212370
PR11912469
PR14612485
PR17012475
PR18712468
PR18812467

Pigment Names
Common Names:

Antique Orange Yellow
Antique Sun Yellow
Azo Yellow Deep
Azo Yellow Orange
Beach Yellow
Benzidine Yellow
Blockx Yellow
Bright Yellow
Cadmium Yellow Deep Hue
Cadmium Yellow Orange (hue)
C.I. Pigment Yellow 83
Deep Yellow
Diarylide HR
Diarylide Yellow
Diarylide Yellow 83
Diarylide Yellow Deep
Diazo Yellow
Disazo Yellow
Gamboge Extra
Hansa Yellow Orange
Indian Yellow (hue)
Indian Yellow Orange (hue)
Indian Yellow Permanent (hue)
Marigold
Opaque Deep Yellow
Permanent Indian Yellow
Permanent Yellow Deep
Pigment Yellow 83
Primary Yellow
Scheveningen Yellow Deep
Stil De Grain Yellow (hue)
Tilt Yellow
Yellow Deep
Yellow Orange Azo

Source

Diarylides are synthetic organic pigments formed by the coupling of tetraazotized benzidines with acetoacetarylides. They are disazo compounds with a backbone structure based on 3,3'-dichlorobenzidine.

Permanence and Compatibility

Diarylides have approximately twice the tinting strength of monoarylides and show improved bleed resistance and thermal stability due to their higher molecular weight.

Oil Absorption and Grinding

Diarylide yellow absorbs a large amount of oil—for every 100 grams of diarylide yellow 58 grams of linseed oil is needed to form a coherent paste, and is the oil absorption value for this pigment.

Toxicity

Diarylide yellow is not considered toxic, however, care should be used in handling the dry powder pigment to avoid inhaling the dust. All toxicological studies showed no signs of toxicity to humans or the environment.

For more information on how to handle pigments safely, please visit How to Safely Handle Art Materials and Pigments.

Ecology

Diarylide yellow is among organic pigments that contain inadvertent polychlorinated biphenyls (PCB) or dichlorobenzidine (DCB) compounds.

More Information
SKU436-11
BrandRublev Colours
VendorNatural Pigments
Processing TimeUsually ships the next business day.
ColorYellow
Pigment TypeOrganic, Synthetic
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Diarylide Yellow Pigment
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