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| Product Name(s) | Smalt, Royal Smalt |
| Product Number(s) | 417-13S, 417-13M, 417-13B, 417-14S, 417-14M, 417-14B |
| Company | Natural Pigments LLC
PO Box 112
Willits, CA 95490
United States of America |
| Technical Phone | 707-459-9998 |
| Fax | 707-275-6063 |
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| Product Name(s) | Smalt, Royal Smalt |
| Synonyms | starch blue, émail, esmail, azur à poudrer, bleu d'émail, Kaiserblau, Königsblau, Azurblau, Sächsischblau, Streublau, Couleur, Eschel |
| Component Name | CAS No. | % Composition Range | OSHA PEL fibers/cc | ACGIH TLV fibers/cc | NIOSH fibers/cc | | Chemical Formula | | | TWA | STEL | TWA | STEL | TWA | STEL | Cobalt Oxide
Co3O4 | 1308-06-1 | Varies | N.E.1 | N.E. | 0.022 | N.E. | N.E. | N.E. | | 1) N.E. = None Established. 2) As Cobalt, listed under "Cobalt, inorganic compounds"). |
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| Inhalation |
| Acute Health Effects | Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. |
| Chronic Health Effects | May cause chronic airway hyperreactivity and asthma, with changes in pulmonary function. Cobalt compounds may cause cancer based upon animal studies. May cause chronic heart disease due to effects on the heart muscle. |
Aggravation of
Pre-existing Conditions | Persons with respiratory function may be more susceptible to the effects of this substance. |
| Ingestion |
| Acute Health Effects | May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. |
| Chronic Health Effects | Long exposure to cobalt and cobalt compounds may cause cancer based upon animal studies. May cause chronic heart disease due to effects on the heart muscle. |
Aggravation of
Pre-existing Conditions | Medical conditions that may be aggravated by exposure: None anticipated. |
| Eye Contact |
| Acute Health Effects | Contact with eye may cause irritation. |
| Chronic Health Effects | Prolonged or repeated contact may cause severe irritation. |
Aggravation of
Pre-existing Conditions | Medical conditions that may be aggravated by exposure: None anticipated. |
| Skin Contact |
| Acute Health Effects | May cause irritation, depending on duration of contact. |
| Chronic Health Effects | May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. |
Aggravation of
Pre-existing Conditions | Persons with pre-existing skin problems may be more susceptible to the effects of this substance. |
| | Health effects described above are based on published scientific information available for review and evaluated on behalf of this product. Actual signs and symptoms experienced may vary due to conditions at the time of exposure. |
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| After Inhalation | Remove to fresh air. If conscious, have victim clear nasal passages. Restore breathing (e.g., artificial respiration, CPR). Seek medical attention, as necessary, if symptoms develop or persist. |
| After Skin Contact | In case of contact, wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Wash clothing before reuse. Call a physician, if irritation occurs. |
| After Eye Contact | Holding eyelids open, do not allow victim to rub their eyes. Gently flush eyes for 15 minutes with large quantities of water. Seek medical attention if irritation develops or persists. |
| After Ingestion | Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Get medical attention if symptoms appear. |
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| Fire | Not considered to be a fire hazard. Not flammable. |
| Explosion | Not considered to be an explosion hazard. |
| Flash Points | Not applicable |
| Auto-Ignition | Not applicable |
| Flammable Limits | Not applicable |
| Extinguishing Media | This material is not combustible and is not anticipated to react with commercially employed extinguishing media. Use appropriate extinguishing media for surrounding fire. |
| Special Fire Fighting Procedure | As part of responding to any fire, firefighters should wear full turnout gear with a positive pressure demand mode Self-Contained Breathing Apparatus (SCBA). Contain all fire suppression run-off. |
Hazardous Thermal
Decomposition Byproducts | No information available |
| Fire/Explosion Hazards | No information available |
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| Spill Procedures | Protect against identified hazards through use of prescribed personal protection equipment, proper work and hygiene practices. Limit foot and vehicular traffic to minimize mechanical agitation and dispersion. Employ a vacuum, equipped with HEPA (High Efficiency Particulate Air) filter, for clean-up of the spill material. If no vacuum is available, use a broom and shovel to collect excess powder in the area. Residual material should then be cleared, utilizing the process of wet sweeping, to avoid dust generation. |
| Containment Techniques | This is a solid material and will not travel far from the spill location unless mechanically agitated. Therefore, no specific containment techniques are recommended outside of restricting access to the spill location. During spill cleanup, residual wash waters should be contained and collected for proper disposal. |
| Spill Response Equipment | The following equipment is recommended for spill response:
• vacuum, equipped with a HEPA filter
• broom, wet mop
• dustpan, shovel, or scoop
• bags, drums, or sacks for collection
Note: Non-sparking equipment may be selected, based on location specific requirements and individual work site evaluations. |
| Personal Protective Equipment | Employees should utilize the following protective equipment when performing spill response activities:
• gloves (rubber or leather)
• cotton or Tyvek coveralls
• chemical/safety impact goggles
• respiratory equipment recommended in Section 8 |
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| Handling | When handling this product, all personnel are directed to:
• Wear all specified elements of PPE, as directed by this document, or under location specific requirements, whichever is more conservative.
• Avoid creating dust, where possible. |
| Storage | The following information provides the appropriate and recommended methods for safe storage and maintenance of product integrity:
• Store in a cool, dry, well-ventilated area.
• Product containers (paper bags, nylon bags, drums, etc.) are prone to physical damage. Care should be taken in storage and handling in order to prevent damage.
• Avoid contact with oxidizers and chemically active metals, since violent reactions may occur. |
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| Engineering Controls | If user operations generate dusts, use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. |
| Respiratory Protection | If the exposure limit is exceeded and engineering controls are not feasible, a full facepiece particulate respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids. glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. |
| Skin Protection | Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. |
| Eye/Face Protection | Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. |
| Work Hygiene Practices | To control potential exposures, avoid creating dust. Always wear appropriate protective equipment when handling. To avoid skin contact, gloves (leather or rubber) should be worn when handling containers of this substance. Do not eat, drink, smoke or apply cosmetics while using/handling. Always wash hands and face after handling.
• Avoid direct skin contact when possible.
• Do not eat, drink, smoke, or perform other hand-to-mouth activities in product use or handling area.
• Wash thoroughly after handling this product. |
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| Appearance | Physical State: Solid
Color: Blue Black
Form: Powder |
| Odor | Odorless |
| Molecular Weight | 240.80 |
| Ph Value | Not applicable. |
| Boiling Point (at 760 mm Hg) | Not applicable. |
| Melting Point | 895° C. (16432° F.) (decomposes) |
| Flash Point | Not applicable. |
| Flammability | Not applicable. |
| Autoignition Temperature | Not applicable. |
| Explosive Properties | Not applicable. |
| Explosion Limits | Not applicable. |
| Vapor Pressure (mm Hg) | Not applicable. |
| Vapor Density (Air=1) | Not applicable. |
| Solubility | Insoluble at 20° C. |
| Specific Gravity/Density | 6.11 g/cm3 |
| Viscosity | Not applicable. |
| Evaporation Rate (BuAc=1) | Not applicable. |
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| Stability | Stable under ordinary conditions of use and storage. |
| Hazardous Decomposition Products | Cobalt and cobalt compounds. |
| Hazardous Polymerization | Will not occur. |
| Incompatibilities | No information available. |
| Conditions to Avoid | No information available. |
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| Occupationally Relevant Routes of Exposure |
| Inhalation | No quantitative information found. |
| Ingestion | CAS No. 1308-06-1:
Oral, rat: LD50 = >5 gm/kg
CAS No. 1307-96-6:
Oral, rat: LD50 = 202 mg/kg
Oral, rat: LD50 = 202 mg/kg |
| Skin | No quantitative information found. |
| Eye | No quantitative information found. |
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| Environmental Fate | Cobalt uptake and phytotoxicity are affected by soil pH. More acidic soils absorb cobalt less strongly. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The products of degradation may be more toxic. |
Distribution and Persistence
in the Environment | No information found. |
Bioaccumulation in
Aquatic Organisms | No information found. |
Permissible Concentration
in Water | No information found. |
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| Physical/Chemical Properties | This material is a stable solid. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. |
| Recommended Disposal Method | Where possible, re-blend spilled, unused, or off-specification materials with other suitable materials in support of waste minimization. Where this is not possible, dispose of material according to Federal (country-specific), state, and local requirements. |
| Empty Containers | This product may be shipped in paper or nylon bags, steel drums, plastic or steel pails, or intermediate bulk containers. All residual material must be emptied and the containers recycled where possible. Where recycling is not possible, containers must be disposed of in accordance with Federal (country-specific), state, and local regulations. If questions exist about disposal, please contact the manufacturer for additional information. |
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| U.S. DOT and IATA | Not regulated as a hazardous material. |
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| U.S. Regulations | TSCA
CAS# 1308-06-1 is listed on the TSCA inventory.
CAS# 1307-96-6 is listed on the TSCA inventory.
Health and Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 1308-06-1: immediate, delayed.
Section 313
This material contains Cobalt oxide Co3O4 (listed as Cobalt compounds), 100%, (CAS# 1308-06-1) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. This material contains Cobalt(II) oxide (listed as Cobalt compounds), -%, (CAS# 1307-96-6) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Clean Air Act:
CAS# 1308-06-1 (listed as Cobalt compounds) is listed as a hazardous air pollutant (HAP).
CAS# 1307-96-6 (listed as Cobalt compounds) is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA. |
| State Regulations | CAS# 1308-06-1 can be found on the following state right to know lists: New Jersey, (listed as Cobalt compounds), Pennsylvania, (listed as Cobalt compounds), Minnesota, (listed as Cobalt, inorganic compounds).
CAS# 1307-96-6 can be found on the following state right to know lists: New Jersey, (listed as Cobalt compounds), Pennsylvania, (listed as Cobalt compounds), Minnesota, (listed as Cobalt, inorganic compounds).
California Prop 65:
WARNING: This product contains Cobalt(II) oxide, a chemical known to the state of California to cause cancer.
California No Significant Risk Level: None of the chemicals in this product are listed. |
| WHMIS | This product has a WHMIS classification of D2B, D2A.
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. |
| European/International Regulations | European Labeling in Accordance with EC Directives:
Hazard Symbols: XN N
Risk Phrases:
R 22 Harmful if swallowed
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases:
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
S 60 This material and its container must be disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1308-06-1: 0
CAS# 1307-96-6: 2
Canada - DSL/NDSL
CAS# 1308-06-1 is listed on Canada's DSL List.
CAS# 1307-96-6 is listed on Canada's DSL List.
Canadian Ingredient Disclosure List
CAS# 1308-06-1 is not listed on the Canadian Ingredient Disclosure List.
CAS# 1307-96-6 is listed on the Canadian Ingredient Disclosure List. |
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| Product Name | Smalt |
| Ingredients | Smalt Asbestos |
| Signal Word | WARNING! |
| Hazard Description | Harmful if swallowed. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Precautions | Do not breathe dust. Avoid contact with skin. Wear suitable gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. |
First Aid
Procedures | In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, DO NOT INDUCE VOMITING. Never give anything by mouth to an unconscious person. In all cases call a physician if symptoms develop. |
| Fire Instructions | This material is not flammable. Select fire extinguishment media for surrounding materials. |
Spill or Leak
Procedures | Wear appropriate protective equipment. Limit foot and vehicular traffic to minimize agitation and dispersion. Employ a vacuum (equipped with a HEPA filter), broom and shovel, and wet sweeping for spill clean-up. Avoid creating dust. Do not allow this product or run-off to reach waterways. |
Handling and
Storage Instructions | Wear specified elements of personal protective equipment, as defined in the Material Safety Data Sheet (MSDS), or follow location specific instructions for handling this product. Store in a cool, dry, well-ventilated area. Specific instructions concerning directions for use and handling may be found in the MSDS or may be supplied by the manufacturer. |
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| HMIS Ratings | Health: 2 (Moderate)
Flammability: 0 (None)
Reactivity: 0 (None)
Personal Protection: E |
| NFPA Ratings | Health: 2 (Moderate)
Flammability: 0 (None)
Reactivity: 0 (None) |
| Date | 24 August 2007 |
| Disclaimer | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Natural Pigments, LLC shall not be held liable for any damage resulting from handling or from contact with the above product.
Copyright 2005-2007 Natural Pigments, LLC. License granted to make unlimited paper copies for internal use only. |
